ACIDS, BASES AND SALTS.

Strength of acids. Acids in aqueous form.

By the end of the lesson, the learner should be able to:


Define an acid in terms of hydrogen ions.

Explain strength of acids in aqueous form in terms of number of hydrogen ions present.

Class experiments: investigate reactions of magnesium and zinc carbonate with different acids.
Make and record observations in tabular form.
Make deductions from the observations.
Write relevant chemical equations and ionic equations.
Detailed discussion leading to the definition of an acid and explanation of strength of an acid.

Magnesium strip, zinc carbonate,
2M HCl,
2M H2SO4,
2M ethanoic acid.

K.L.B. BK IV
Pages 1-4

ACIDS, BASES AND SALTS.

pH values of acids. Electrical conductivities of aqueous acids.

By the end of the lesson, the learner should be able to:
Determine strength of acids using pH values.

Determine strengths of acids by comparing their electrical conductivities.

Classify acids as either strong or weak in terms of partial dissociations in aqueous solutions.

Q/A: review determination of strength of acids using a litmus paper and pH scale.
Class / group experiments: record colour of universal indicator in
2M HCl and 2M ethanoic acid.
Set up voltameters of 2M HCl and 2M ethanoic acid in turns.
Record amounts of current .
Discuss the observations.
Write corresponding ionic equations.

Universal
indicator,
2M HCl,
2M ethanoic acid,
dry cells,
carbon electrodes,
milli-ammeters,
wires, switches etc.

K.L.B. BK IV
Pages 4-6

ACIDS, BASES AND SALTS.

Definition of a base in terms of hydroxide ions.
Neutralization reaction.

By the end of the lesson, the learner should be able to:
Define a base in terms of hydroxide ions.
Determine the results of reaction of an acid and a base.

Teacher demonstration:
Dissolve calcium hydroxide in water.
Carry out litmus test on the resulting solution.
Discuss the results; hence define a base in terms of hydroxide ions.

Add 1M HCl to an aqueous solution of Calcium hydroxide drop wise until colour, change of the universal indicator is noted.
Write ionic equation for the reaction.

Red litmus paper, calcium hydroxide solid.
1M HCl,
Calcium hydroxide,
universal indicator.

K.L.B. BK IV
Pages 6-7
K.L.B. BK IV
Page 7

ACIDS, BASES AND SALTS.

Strength of bases.

By the end of the lesson, the learner should be able to:
Compare strengths of bases using pH values and electrical conductivity.


Classify bases/ alkali as either strong or weak in terms of complete / partial ionization.

Carry out pH tests of 2M NaOH and 2M ammonia solution using universal indicator solutions; and observe colour changes.

Carry out electrical conductivity tests of voltameters of the above solutions.

Discussion: relate number of hydroxide ions to pH values and electrical conductivity of bases.

2M NaOH,
2M ammonia solution, universal indicator solutions, dry cells,
carbon electrodes,
milliammeters,
wires, switches etc

K.L.B. BK IV
Pages 7-9

ACIDS, BASES AND SALTS.

Dissolving hydrogen chloride gas in water / methylbenzene.

By the end of the lesson, the learner should be able to:
Define a polar and a non-polar solvent.

Teacher demonstration:
Dissolving HCl gas in different solvents.
Discuss the observations.
Write down related balanced chemical equations.

Ammonia gas,
Methylbenzene, hydrogen chloride gas.

K.L.B. BK IV
Pages 9-11

ACIDS, BASES AND SALTS.

Dissolving ammonia gas in water/ methylbenzene.

By the end of the lesson, the learner should be able to:
Investigate effect of a polar / non-polar solvent on ammonia gas.

Carry out litmus tests on the resulting solution.
Make observations and deductions thereof.
Write down related balanced chemical equations.

Ammonia gas,
Methylbenzene.

K.L.B. BK IV
Pages 11-12

ACIDS, BASES AND SALTS.

Amphoteric oxides.
Precipitation Reactions.

By the end of the lesson, the learner should be able to:
Define an amphoteric oxide.
Identify some amphoteric oxides.

Define a precipitate.
Write ionic equations showing formation of precipitates.

Class experiment:
Carry out acid / base reactions with metal oxides.
Q/A: make deductions from the results.
Writing and balancing relevant equations.


Q/A: review definition of a salt.
Class experiment;
Add sodium carbonate or a suitable carbonate to various salt solutions containing Mg2+, Al3+, Ca2+, etc.
Make observations and discuss the results.

2M Nitric acid
2M NaOH,
HNO3.
Amphoteric oxides.
Soluble carbonates e.g. Na2CO3, K2CO3, (NH4)2CO3
Salt solutions containing Mg2+, Al3+, Ca2+, etc.

K.L.B. BK IV
Pages 12-14
K.L.B. BK IV
Pages 14-16

ACIDS, BASES AND SALTS.

Solubility of chlorides sulphites and sulphates.

By the end of the lesson, the learner should be able to:
Find out cations that form (in)soluble chlorides, sulphates and sulphites.

Class experiments: measure 2cc of 0.1M solution containing Pb2+ into a test tube.
Add drops of 2M NaCl solution.
(Later 2M Sodium Sulphate and 2M Sodium Sulphate).
Warm the mixture and make observations.
Repeat the procedure using other salt solutions containing other ions.
Tabulate the results.

0.1M solution containing Pb2+, 2M NaCl solution, 2M sodium sulphate, source of heating.

K.L.B. BK IV
Pages 16-17

ACIDS, BASES AND SALTS.

Equations for formation of insoluble chlorides, sulphites and sulphates.

By the end of the lesson, the learner should be able to:
Write down equations for formation of insoluble chlorides, sulphites and sulphates.

Q/A: review observations made in the above experiments.
Discuss the solubility of the cations.
Write relevant ionic equations.

student book

K.L.B. BK IV
Pages 17-18

ACIDS, BASES AND SALTS.

Complex ions.

By the end of the lesson, the learner should be able to:
Explain formation of complex ions.

Add drops of 2M sodium hydroxide / 2M ammonia solution to a solution containing Mg2+, Zn2+, etc.

Make observations and discuss the results.

2M Sodium hydroxide (2M ammonia solution),
solution containing Mg2+, Zn2+, etc.

K.L.B. BK IV
Pages 18-20

ACIDS, BASES AND SALTS.

Solubility of a salt at a given temperature.
Problems solving on solubility.

By the end of the lesson, the learner should be able to:
Define the term solubility.
Determine solubility of a given salt at room temperature.
Solve problems involving solubility of a solute in a solvent at a given temperature.

Q/A: review the terms saturated, unsaturated solutions & crystallization.
Class experiment: determine mass of a solute that dissolves in 100cc of water at room temperature.

Worked examples.
Supervised practice.
Written assignment.

Suitable solutes.
Evaporating dish, watch glass, heating source, thermometer.

K.L.B. BK IV
Pages 20-21
K.L.B. BK IV
Pages 21-22

ACIDS, BASES AND SALTS.

Effect of temperature on solubility of a solute in a solvent.

By the end of the lesson, the learner should be able to:
Investigate the effect of temperature on solubility of a solute in a solvent.

Experiments involving solubility of KClO3 at different temperatures.
Note temperatures at which crystallization occurs.
Oral questions and discussion.

KClO3 thermometers, source of heat.

K.L.B. BK IV
Pages 22-25

ACIDS, BASES AND SALTS.

Effects of various salts on soap.

By the end of the lesson, the learner should be able to:
Determine the effects of various salts on soap.

Group experiments: form soap lather in distilled water, tap water, rainwater, dilute solution of sodium chloride and solutions containing Ca2+ and Zn2+.
Note volume of soap that forms lather readily.

distilled water, tap water, rainwater, dilute solution of sodium chloride and solutions containing Ca2+ and Zn2+.

K.L.B. BK IV
Pages 25-27

ACIDS, BASES AND SALTS.
ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Removal of hardness of water.
Endothermic and Exothermic Reactions.

By the end of the lesson, the learner should be able to:
Identify ions for hardness of water.
Identify methods of removing hardness of water.
State merits & demerits of hard water.
To differentiate between endothermic & exothermic reactions.

Review results of above experiments.
Probing questions & brief discussion.
Assignment.
Investigate temperature changes in solution formation.
Obtain changes in temperature when ammonium nitrate and sodium hydroxide are dissolved in water, one at a time.

student book
Ammonium nitrate,
Sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 27-29

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Energy level diagrams.
Enthalpy Notation. Change of state.

By the end of the lesson, the learner should be able to:
Represent endothermic reactions with exothermic reactions with energy level diagrams.

Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Probing questions on relative energies of reactants and products in endothermic and exothermic and endothermic reactions.
Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

student book
Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 33-35
K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

CAT

By the end of the lesson, the learner should be able to:

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of given substances.

Dissolve known masses of ammonia nitrate / sodium hydroxide in known volumes of water.
Determine temperature changes.
Calculate molar heat of solution. Supervised practice.

Ammonia nitrate / sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 40-41

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of H2SO4.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of H2SO4.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Conc. H2SO4, thermometers.

K.L.B. BK IV
Pages 42-45

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of H2SO4.
Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of H2SO4.
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Conc. H2SO4, thermometers.
Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 42-45
K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Standard enthalpy changes.
Hess?s Law.

By the end of the lesson, the learner should be able to:
Define the term standard enthalpy change.
Denote standard enthalpy change with the correct notation.

State Hess?s law.

Solve problems related to Hess?s law.

Exposition & brief discussion.
Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

student book

K.L.B. BK IV
Pages 54-56
K.L.B. BK IV
Pages 56-57

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat of solution hydration energy and lattice energy.

By the end of the lesson, the learner should be able to:
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat values of fuels.

By the end of the lesson, the learner should be able to:
Define the term fuel.
Describe energy changes when a fuel undergoes combustion.
Outline factors considered when choosing a suitable fuel.

Probing questions and brief discussion.

student book

K.L.B. BK IV
Pages 64-66

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Environmental effects of fuels.

By the end of the lesson, the learner should be able to:
Outline some environmental effects of fuels.
Identify measures taken to reduce environmental
pollution.

Q/A & open discussion.

student book

K.L.B. BK IV
Pages 67-68

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of concentration on rate of a reaction
Effect of time of reaction on the rate of reaction.
Effect of temperature of reactants on rate of reaction.

By the end of the lesson, the learner should be able to:





Explain the effects of change of concentration of reactants on a reaction.

Explain how the rate or reaction changes as the reaction proceed
Explain the effect of temperature on rate of reaction.

Group experiments to investigate effect of concentration on rate of reaction using dil. HCl and magnesium ribbons.
Determine the time taken for reactions to be complete.
Calculation of concentration of HCl in moles per litre.
Discuss the observations and sketch illustrative graphs.

Group experiments: investigate volume of gas evolved when magnesium reacts with dilute HCl.
Collect evolved gas and sketch and illustrative graphs.
Discuss the results.
Group experiments: investigate the effects of temperature on the rate of reaction of sodium thiosulphate with dilute HCl.
Sketch and interpret relevant graphs.
Discuss the collision theory and effects of activation energy.

Portions of 2M HCl diluted with different volumes of water,
Stopwatches.
Magnesium ribbons, stopwatches, conical flask.
100cm3 0.5M HCl, syringes, stoppers, tubes and connectors.
Sodium thiosulphate heated at different temperatures, dilute HCl, stopwatches.
Graph papers.

K.L.B. BK IV
Pages 73-74
K.L.B. BK IV
Pages 75-79

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change in surface area of reactants on the rate of a reaction.

By the end of the lesson, the learner should be able to:
Explain the effect of change in surface area on the rate of a reaction.

Group experiment/ teacher demonstration.

Compare reactions of marble chips with dilute HCl and that of marble chips powder with equally diluted HCl.

Collect evolved gas in each case.

Teacher asks probing questions related to the observations made.

Marble chips, marble chips powder, syringes, conical flasks with stoppers, 1M HCl.

K.L.B. BK IV
Pages 83-85

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of a suitable catalyst on the rate of a reaction
Effect of light on rate of specific reactions.
Reversible reactions.

By the end of the lesson, the learner should be able to:
Explain effects of a suitable catalyst on the rate of a reaction.
Identify reactions that are affected by light.
Write down equations for reversible reactions.

Teacher demonstration: preparation and collection of oxygen gas without using a catalyst, then using manganese (IV) oxide as a catalyst.
Explain the results in terms of activation energy.
Teacher demonstration: decomposition of silver bromide in the presence of light.
Mention other examples of reactions affected by light.
Q/A: review temporary and permanent changes.
Teacher demonstration: heating crystals of hydrated copper (II) sulphate, then ?hydrating? them.
Write the corresponding chemical equations.
Give further examples of reversible reactions.

Hydrogen peroxide, manganese (IV) oxide.
Silver bromide.
Crystals of hydrated copper (II) sulphate.

K.L.B. BK IV
Pages 85-88
K.L.B. BK IV
Pages 91-93

RATES OF REACTION & REVERSIBLE REACTIONS.

State of equilibrium in chemical reactions.
Le Chatelier?s Principle.

By the end of the lesson, the learner should be able to:
Define the term equilibrium as used in reversible reactions.
Write down equations of reversible reactions in a state of equilibrium.
State Le Chatelier?s Principle.

Brief discussion, giving examples of chemical equations for reversible reactions.
Investigate the effect of change of concentration of reactants on equilibrium.
Add 2M sodium hydroxide in steps to bromine water.
Make and record observations.
Discuss the results leading to
Le Chatelier?s Principle.

student book
Add 2M sodium hydroxide,

K.L.B. BK IV
Pages 94-95

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change of pressure and temperature on equilibrium shift.

By the end of the lesson, the learner should be able to:
Explain the effect of change of pressure & te,perature on equilibrium shift.

Q/A: review kinetic theory of matter.
Q/A & discussion on effect of change of pressure / temperature on shifting of equilibrium; giving specific examples of chemical equations.
Written assignment.

student book

K.L.B. BK IV
Pages 97-101

RATES OF REACTION & REVERSIBLE REACTIONS.

The Haber Process.
The Contact Process.

By the end of the lesson, the learner should be able to:
Explain the concept optimum conditions of a chemical equilibrium.
Explain factors that change the position of equilibrium of the Harber process.
Explain how change of temperature and pressure affect rate of manufacture of sulphur (VI) acid.

Q/A and detailed discussion on change of pressure, temperature, concentration of ammonia and effect of presence of a suitable catalyst on the Haber process.
Probing questions and brief discussion.
Assignment.

student book

K.L.B. BK IV
Pages 102-103

ELECTRO-CHEMISTRY.

Redox reactions.
Oxidizing Numbers.

By the end of the lesson, the learner should be able to:


Describe redox reactions in terms of gain / loss of electrons.
Identify oxidizing / reducing agents involved in redox reactions.

Outline rules of assigning oxidation numbers.
Determine the oxidation numbers of an element in a given compound.
Explain the use of oxidation numbers in naming compounds.

Q/A: review cations, anions and charges.
Write down ionic half equations and identify reducing / oxidizing agents.
Exposition and giving specific examples.
Work out oxidizing number of elements in given compounds.
Copy and complete a table of compounds containing elements that more than one oxidation number.

student book

K.L.B. BK IV
Pages 108-9
K.L.B. BK IV
Pages 109-116

ELECTRO-CHEMISTRY.

Displacement reactions.

By the end of the lesson, the learner should be able to:
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.

Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.

K.L.B. BK IV
Pages 116-120

ELECTRO-CHEMISTRY.

The oxidizing power of an element.
Cell diagrams.

By the end of the lesson, the learner should be able to:
Arrange elements in order of their oxidizing power.
Define the terms electrode, potential and e.m.f. of an electrochemical cell.
Describe components of a cell diagram.
Draw cell diagrams using correct notations.

Teacher demonstration / group expts:
Adding halogens to solutions containing halide ions.
Tabulate the results.
Discuss the results and arrive at the oxidizing power series of halogens.
Teacher demonstration: Zinc/ copper cell.
Q/A & discussion: changes in oxidation numbers.
Exposition: cell diagram and deducing the direction of electron flow.

Halogens:
Cl2 (g),
Br2 (l),
I2 (s).
Halides:
KCl, KBr, KI.
Zinc/ copper cell.

K.L.B. BK IV
Pages 120-122

ELECTRO-CHEMISTRY.

Standard Electrode Potentials.

By the end of the lesson, the learner should be able to:
Identify standard conditions for measuring electrode potentials.
Define the term standard electrode potential of a cell.
Write half reactions of electrochemical cells.

Descriptive and expository approaches: teacher exposes new concepts.

student book

K.L.B. BK IV
Pages 129-131

ELECTRO-CHEMISTRY.

Standard electrode potential series.
Emf of a cell.

By the end of the lesson, the learner should be able to:
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.
Calculate emf of a cell using standard electrodes potentials.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

Q/A: review half-cells.
Worked examples; supervised practice.
Assignment.

student book

K.L.B. BK IV
Pages 131-133
K.L.B. BK IV
Pages 133-136

ELECTRO-CHEMISTRY.

Possibility of a reaction to take place.
Primary and secondary chemical cells.

By the end of the lesson, the learner should be able to:
Predict whether a reaction will take place or not using standard electrode potentials.
Describe the functioning of primary and secondary chemical cells.

Worked examples.
Oral exercise.
Assignment.
Exposition of new concepts and brief discussion

student book

K.L.B. BK IV
Pages 136-137

ELECTRO-CHEMISTRY.

Electrolysis of dilute NaCl.

By the end of the lesson, the learner should be able to:
Define the term electrolysis.
Explain the concept of preferential discharge of ions.

Teacher demonstration: electrolysis of dilute sodium chloride with carbon electrodes.
Test for gases collected.
Write down equations of reactions at each electrode.
Discussion: preferential discharge of ions at electrodes.

Dilute sodium chloride voltameter.

K.L.B. BK IV
Pages 141-144

ELECTRO-CHEMISTRY.

Electrolysis of brine.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of brine.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Brine voltameter.

K.L.B. BK IV
Pages 144-146

ELECTRO-CHEMISTRY.

Electrolysis of dilute sulphuric (VI) acid.
Factors affecting electrolysis.
Application of electrolysis.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of dilute sulphuric (VI) acid.
Explain factors that affect electrolytic products discharged at electrodes.
Describe some applications of electrolysis.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Q/A: review the electrochemical series of elements.
Teacher writes down order of ease of discharge of ions at electrodes.
Discussion: other factors; giving suitable examples.
Probing questions and brief discussion on applications of electrolysis.
Practical assignment on electrolysis: electroplating an iron nail with a suitable metal.

Sulphuric acid voltameter.
student book
Suitable voltameter.

K.L.B. BK IV
Pages 146-148
K.L.B. BK IV
Pages 153-5

ELECTRO-CHEMISTRY.

Faraday?s law of electrolysis.

By the end of the lesson, the learner should be able to:
State Faraday?s law of electrolysis.
Solve problems related to Faraday?s law of electrolysis.

Discuss above results, leading to Faraday?s law of electrolysis.

Worked examples.

Assignment.

Weighing balance, stop watch, copper sulphate voltameter.

K.L.B. BK IV
Pages 161-4