THE MOLE

Relative Mass - Introduction and Experimental Investigation
Avogadro's Constant and the Mole Concept
Interconversion of Mass and Moles for Elements

By the end of the lesson, the learner should be able to:
Define relative mass using practical examples
Compare masses of different objects using a reference standard
Explain the concept of relative atomic mass
Identify carbon-12 as the reference standard
Define Avogadro's constant and its value
Explain the concept of a mole as a counting unit
Relate molar mass to relative atomic mass
Calculate number of atoms in given masses of elements

Experiment: Weighing different sized nails using beam balance. Use smallest nail as reference standard. Q/A: Discuss everyday examples of relative measurements. Teacher exposition: Introduction of carbon-12 scale and IUPAC recommendations. Calculate relative masses from experimental data.
Experiment: Determine number of nails with mass equal to relative mass in grams. Teacher exposition: Introduce Avogadro's constant (6.023 × 10²³). Discussion: Mole as counting unit like dozen. Worked examples: Calculate moles from mass and vice versa.

Different sized nails ( 5-15cm), Beam balance, Fruits of different masses, Reference charts
Beam balance, Various sized nails, Scientific calculators, Avogadro's constant charts
Scientific calculators, Periodic table, Worked example charts, Formula triangles

KLB Secondary Chemistry Form 3, Pages 25-27
KLB Secondary Chemistry Form 3, Pages 27-30

THE MOLE

Molecules and Moles - Diatomic Elements
Empirical Formula - Experimental Determination

By the end of the lesson, the learner should be able to:
Distinguish between atoms and molecules
Define relative molecular mass
Calculate moles of molecules from given mass
Determine number of atoms in molecular compounds

Discussion: Elements existing as molecules (O₂, H₂, N₂, Cl₂). Teacher exposition: Difference between atomic and molecular mass. Worked examples: Calculate moles of molecular elements. Problem solving: Number of atoms in molecular compounds.

Molecular models, Charts showing diatomic elements, Scientific calculators
Crucible and lid, Magnesium ribbon, Bunsen burner, Beam balance, Tongs, Safety equipment

KLB Secondary Chemistry Form 3, Pages 29-30

THE MOLE

Empirical Formula - Reduction Method
Empirical Formula - Percentage Composition Method
Molecular Formula - Determination from Empirical Formula

By the end of the lesson, the learner should be able to:
Determine empirical formula using reduction reactions
Calculate empirical formula from reduction data
Apply reduction method to copper oxides
Analyze experimental errors and sources

Experiment: Reduction of copper(II) oxide using laboratory gas. Measure masses before and after reduction. Calculate moles of copper and oxygen. Determine empirical formula from mole ratios. Discuss experimental precautions.

Combustion tube, Porcelain boat, Copper(II) oxide, Laboratory gas, Beam balance, Bunsen burner
Scientific calculators, Percentage composition charts, Worked example displays
Scientific calculators, Molecular mass charts, Worked example displays

KLB Secondary Chemistry Form 3, Pages 35-37

THE MOLE

Molecular Formula - Combustion Analysis
Concentration and Molarity of Solutions

By the end of the lesson, the learner should be able to:
Determine molecular formula from combustion data
Calculate moles of products in combustion
Relate product moles to reactant composition
Apply combustion analysis to hydrocarbons

Worked examples: Hydrocarbon combustion producing CO₂ and H₂O. Calculate moles of C and H from product masses. Determine empirical formula, then molecular formula. Practice: Various combustion analysis problems.

Scientific calculators, Combustion analysis charts, Molecular models of hydrocarbons
Scientific calculators, Molarity charts, Various salt samples for demonstration

KLB Secondary Chemistry Form 3, Pages 40-41

THE MOLE

Preparation of Molar Solutions
Dilution of Solutions
Stoichiometry - Experimental Determination of Equations
Stoichiometry - Precipitation Reactions
Stoichiometry - Gas Evolution Reactions

By the end of the lesson, the learner should be able to:
Describe procedure for preparing molar solutions
Use volumetric flasks correctly
Calculate masses needed for specific molarities
Prepare standard solutions accurately
Investigate stoichiometry of precipitation reactions
Determine mole ratios from volume measurements
Write ionic equations for precipitation
Analyze limiting and excess reagents

Experiment: Prepare 1M, 0.5M, and 0.25M NaOH solutions in different volumes. Use volumetric flasks of 1000cm³, 500cm³, and 250cm³. Calculate required masses. Demonstrate proper dissolution and dilution techniques.
Experiment: Pb(NO₃)₂ + KI precipitation reaction. Use different volumes to determine stoichiometry. Measure precipitate heights. Plot graphs to find reaction ratios. Identify limiting reagents.

Volumetric flasks (250, 500, 1000cm³), Sodium hydroxide pellets, Beam balance, Wash bottles, Beakers
Volumetric flasks, Hydrochloric acid (2M), Measuring cylinders, Pipettes, Safety equipment
Iron filings, Copper(II) sulphate solution, Beam balance, Beakers, Filter equipment
Test tubes, Lead(II) nitrate solution, Potassium iodide solution, Burettes, Ethanol, Rulers
Conical flask, Thistle funnel, Plastic bags, Rubber bands, Sodium carbonate, HCl solution

KLB Secondary Chemistry Form 3, Pages 43-46
KLB Secondary Chemistry Form 3, Pages 53-56

THE MOLE

Volumetric Analysis - Introduction and Apparatus
Titration - Acid-Base Neutralization

By the end of the lesson, the learner should be able to:
Define volumetric analysis and titration
Identify and use titration apparatus correctly
Explain functions of pipettes and burettes
Demonstrate proper reading techniques

Practical session: Familiarization with pipettes and burettes. Practice filling and reading burettes accurately. Learn proper meniscus reading. Use pipette fillers safely. Rinse apparatus with appropriate solutions.

Pipettes (10, 20, 25cm³), Burettes (50cm³), Pipette fillers, Conical flasks, Various solutions
Burettes, Pipettes, 0.1M NaOH, 0.1M HCl, Phenolphthalein indicator, Conical flasks

KLB Secondary Chemistry Form 3, Pages 58-59

THE MOLE

Titration - Diprotic Acids
Standardization of Solutions
Back Titration Method

By the end of the lesson, the learner should be able to:
Investigate titrations involving diprotic acids
Determine basicity of acids from titration data
Compare volumes needed for mono- and diprotic acids
Write equations for diprotic acid reactions

Experiment: Titrate 25cm³ of 0.1M NaOH with 0.1M H₂SO₄. Compare volume used with previous HCl titration. Calculate mole ratios. Explain concept of basicity. Introduce dibasic and tribasic acids.

Burettes, Pipettes, 0.1M H₂SO₄, 0.1M NaOH, Phenolphthalein, Basicity reference chart
Anhydrous Na₂CO₃, Approximately 0.1M HCl, Methyl orange, Volumetric flasks, Analytical balance
Metal carbonate sample, 0.5M HCl, 0M NaOH, Phenolphthalein, Conical flasks

KLB Secondary Chemistry Form 3, Pages 62-65

THE MOLE

Redox Titrations - Principles
Redox Titrations - KMnO₄ Standardization

By the end of the lesson, the learner should be able to:
Explain principles of redox titrations
Identify color changes in redox reactions
Understand self-indicating nature of some redox reactions
Write ionic equations for redox processes

Teacher exposition: Redox titration principles. Demonstrate color changes: MnO₄⁻ (purple) → Mn²⁺ (colorless), Cr₂O₇²⁻ (orange) → Cr³⁺ (green). Discussion: Self-indicating reactions. Write half-equations and overall ionic equations.

Potassium manganate(VII), Potassium dichromate(VI), Iron(II) solutions, Color change charts
Iron(II) ammonium sulfate, KMnO₄ solution, Dilute H₂SO₄, Pipettes, Burettes

KLB Secondary Chemistry Form 3, Pages 68-70

THE MOLE
THE MOLE
ORGANIC CHEMISTRY I

Water of Crystallization Determination
Atomicity and Molar Gas Volume
Combining Volumes of Gases - Experimental Investigation
Gas Laws and Chemical Equations
Introduction to Organic Chemistry and Hydrocarbons

By the end of the lesson, the learner should be able to:
Determine water of crystallization in hydrated salts
Use redox titration to find formula of hydrated salt
Calculate value of 'n' in crystallization formulas
Apply analytical data to determine complete formulas
Investigate Gay-Lussac's law experimentally
Measure combining volumes of reacting gases
Determine simple whole number ratios
Write equations from volume relationships

Experiment: Determine 'n' in FeSO₄(NH₄)₂SO₄·nH₂O. Dissolve known mass in acid, titrate with standardized KMnO₄. Calculate moles of iron(II), hence complete formula. Compare theoretical and experimental values.
Experiment: React NH₃ and HCl gases in measured volumes. Observe formation of NH₄Cl solid. Measure residual gas volumes. Determine combining ratios. Apply to other gas reactions.

Hydrated iron(II) salt, Standardized KMnO₄, Dilute H₂SO₄, Analytical balance
Gas syringes (50cm³), Various gases, Analytical balance, Gas supply apparatus
Gas syringes, Dry NH₃ generator, Dry HCl generator, Glass connecting tubes, Clips
Scientific calculators, Gas law charts, Volume ratio examples
Carbon models, Hydrocarbon structure charts, Molecular model kits

KLB Secondary Chemistry Form 3, Pages 72-73
KLB Secondary Chemistry Form 3, Pages 75-77

ORGANIC CHEMISTRY I

Sources of Alkanes - Natural Gas, Biogas, and Crude Oil
Fractional Distillation of Crude Oil

By the end of the lesson, the learner should be able to:
Identify natural sources of alkanes
Describe composition of natural gas and biogas
Explain crude oil as major source of alkanes
Describe biogas digester and its operation

Discussion: Natural gas composition (80% methane). Explanation: Biogas formation from organic waste decomposition. Teacher demonstration: Biogas digester model/diagram. Q/A: Environmental benefits of biogas production.

Biogas digester model/diagram, Natural gas composition charts, Organic waste samples
Crude oil sample, Boiling tubes, High-temperature thermometer, Sand/porcelain chips, Bunsen burner, Test tubes

KLB Secondary Chemistry Form 3, Pages 86-87

ORGANIC CHEMISTRY I

Cracking of Alkanes - Thermal and Catalytic Methods
Alkane Series and Homologous Series Concept

By the end of the lesson, the learner should be able to:
Define cracking of alkanes
Distinguish between thermal and catalytic cracking
Write equations for cracking reactions
Explain industrial importance of cracking

Teacher exposition: Definition and purpose of cracking. Discussion: Thermal vs catalytic cracking conditions. Worked examples: Cracking equations producing smaller alkanes, alkenes, and hydrogen. Q/A: Industrial applications and hydrogen production.

Cracking process diagrams, Chemical equation charts, Catalyst samples for demonstration
Alkane series chart, Molecular formula worksheets, Periodic table

KLB Secondary Chemistry Form 3, Pages 89-90

ORGANIC CHEMISTRY I

Nomenclature of Alkanes - Straight Chain and Branched
Isomerism in Alkanes - Structural Isomers
Laboratory Preparation of Methane

By the end of the lesson, the learner should be able to:
Name straight-chain alkanes using IUPAC rules
Identify parent chains in branched alkanes
Name branched alkanes with substituent groups
Apply systematic naming rules correctly

Teacher demonstration: Step-by-step naming of branched alkanes. Rules application: Longest chain identification, numbering from nearest branch, substituent naming. Practice exercises: Various branched alkane structures. Group work: Name complex branched alkanes.

Structural formula charts, IUPAC naming rules poster, Molecular model kits
Molecular model kits, Isomerism charts, Structural formula worksheets
Sodium ethanoate, Soda lime, Round-bottomed flask, Gas collection apparatus, Bromine water, Wooden splints

KLB Secondary Chemistry Form 3, Pages 90-92

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethane
Physical Properties of Alkanes
Chemical Properties of Alkanes - Combustion and Substitution
Uses of Alkanes in Industry and Daily Life
Introduction to Alkenes and Functional Groups

By the end of the lesson, the learner should be able to:
Prepare ethane using sodium propanoate and soda lime
Compare preparation methods of methane and ethane
Test properties of ethane gas
Write general equation for alkane preparation
Write equations for complete and incomplete combustion
Explain substitution reactions with halogens
Describe conditions for halogenation reactions
Name halogenated alkane products

Experiment: Prepare ethane from sodium propanoate and soda lime. Compare with methane preparation method. Carry out similar tests as for methane. Discussion: General pattern for alkane preparation from sodium alkanoates.
Worked examples: Combustion equations for various alkanes. Teacher demonstration: Methane + bromine in sunlight (or simulation). Discussion: Free radical mechanism in substitution. Practice: Write equations for chlorination of methane.

Sodium propanoate, Soda lime, Gas collection apparatus, Testing materials
Physical properties data tables, Graph paper, Calculators, Solubility demonstration materials
Molecular models, Halogenation reaction charts, Chemical equation worksheets
Industrial application charts, Product samples, Environmental impact materials
Alkene series charts, Molecular models showing double bonds, Functional group posters

KLB Secondary Chemistry Form 3, Pages 94-96
KLB Secondary Chemistry Form 3, Pages 97-98

ORGANIC CHEMISTRY I

Nomenclature of Alkenes
Isomerism in Alkenes - Branching and Positional

By the end of the lesson, the learner should be able to:
Apply IUPAC rules for naming alkenes
Number carbon chains to give lowest numbers to double bonds
Name branched alkenes with substituents
Distinguish position isomers of alkenes

Teacher demonstration: Step-by-step naming of alkenes. Rules application: Longest chain with double bond, numbering from end nearest double bond. Practice exercises: Name various alkene structures. Group work: Complex branched alkenes with substituents.

IUPAC naming charts for alkenes, Structural formula worksheets, Molecular model kits
Molecular model kits, Isomerism worksheets, Geometric isomer models

KLB Secondary Chemistry Form 3, Pages 101-102

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethene
Alternative Preparation of Ethene and Physical Properties

By the end of the lesson, the learner should be able to:
Prepare ethene by dehydration of ethanol
Describe role of concentrated sulfuric acid
Set up apparatus safely for ethene preparation
Test physical and chemical properties of ethene

Experiment: Dehydration of ethanol using concentrated H₂SO₄ at 170°C. Use sand bath for controlled heating. Pass gas through NaOH to remove impurities. Tests: Bromine water, acidified KMnO₄, combustion. Safety precautions with concentrated acid.

Ethanol, Concentrated H₂SO₄, Round-bottomed flask, Sand bath, Gas collection apparatus, Testing solutions
Aluminum oxide catalyst, Glass wool, Alternative apparatus setup, Physical properties charts

KLB Secondary Chemistry Form 3, Pages 102-104

ORGANIC CHEMISTRY I

Chemical Properties of Alkenes - Addition Reactions
Oxidation Reactions of Alkenes and Polymerization
Tests for Alkenes and Uses

By the end of the lesson, the learner should be able to:
Explain addition reactions due to C=C double bond
Write equations for halogenation of alkenes
Describe hydrogenation and hydrohalogenation
Explain addition mechanism

Teacher exposition: Addition reactions definition and mechanism. Worked examples: Ethene + Cl₂, Br₂, HBr, H₂. Discussion: Markovnikov's rule for unsymmetrical addition. Practice: Various addition reaction equations.

Addition reaction charts, Mechanism diagrams, Chemical equation worksheets
Oxidizing agents for demonstration, Polymer samples, Polymerization charts, Monomer-polymer models
Test alkenes, Bromine water, Acidified KMnO₄, Plastic samples, Uses reference charts

KLB Secondary Chemistry Form 3, Pages 105-107

ORGANIC CHEMISTRY I

Introduction to Alkynes and Triple Bond
Nomenclature and Isomerism in Alkynes
Laboratory Preparation of Ethyne
Physical and Chemical Properties of Alkynes

By the end of the lesson, the learner should be able to:
Define alkynes and triple bond structure
Write general formula for alkynes (CₙH₂ₙ₋₂)
Identify first members of alkyne series
Compare degree of unsaturation in hydrocarbons
Prepare ethyne from calcium carbide and water
Set up gas collection apparatus safely
Test physical and chemical properties of ethyne
Write equation for ethyne preparation

Teacher exposition: Alkynes definition and C≡C triple bond. Table study: First 6 members of alkyne series with structures. Discussion: Degrees of unsaturation - alkanes vs alkenes vs alkynes. Model demonstration: Triple bond representation.
Experiment: Calcium carbide + water reaction. Use sand layer for heat absorption. Collect ethyne over water. Tests: Color, smell, combustion, bromine water, acidified KMnO₄. Safety: Dry apparatus, controlled water addition.

Alkyne series charts, Triple bond molecular models, Unsaturation comparison charts
IUPAC naming rules for alkynes, Structural formula worksheets, Molecular model kits
Calcium carbide, Sand, Flat-bottomed flask, Dropping funnel, Gas collection apparatus, Testing solutions
Physical properties charts, Comparison tables, Combustion equation examples

KLB Secondary Chemistry Form 3, Pages 109-110
KLB Secondary Chemistry Form 3, Pages 111-112

ORGANIC CHEMISTRY I
NITROGEN AND ITS COMPOUNDS

Addition Reactions of Alkynes and Chemical Tests
Uses of Alkynes and Industrial Applications
Uses of Nitric(V) Acid and Introduction to Nitrates

By the end of the lesson, the learner should be able to:
Write equations for halogenation of alkynes
Describe hydrogenation and hydrohalogenation
Compare reaction rates: alkynes vs alkenes
Perform chemical tests for alkynes

Worked examples: Two-step addition reactions of ethyne with Br₂, Cl₂, H₂. Discussion: Faster reaction rates in alkynes compared to alkenes. Practical session: Test alkynes with oxidizing agents. Comparison: Rate of decolorization vs alkenes.

Addition reaction charts, Chemical equation worksheets, Test solutions, Stopwatch for rate comparison
Industrial application charts, Welding equipment demonstration/video, Synthetic fiber samples
Industrial use charts, Nitrate salt samples, Preparation method diagrams, Safety data sheets

KLB Secondary Chemistry Form 3, Pages 113-115

NITROGEN AND ITS COMPOUNDS

Action of Heat on Nitrates - Decomposition Patterns
Test for Nitrates - Brown Ring Test

By the end of the lesson, the learner should be able to:
Test thermal decomposition of different nitrates
Classify decomposition patterns based on metal reactivity
Identify products formed on heating
Write equations for decomposition reactions

Experiment: Heat KNO₃, NaNO₃, Zn(NO₃)₂, Cu(NO₃)₂, NH₄NO₃ separately. Test gases with glowing splint. Observe residues. Classification: Group I nitrates → nitrite + O₂; Group II → oxide + NO₂ + O₂; NH₄NO₃ → N₂O + H₂O.

Various nitrate salts, Test tubes, Bunsen burner, Gas collection apparatus, Glowing splints, Observation recording sheets
Sodium nitrate, Fresh FeSO₄ solution, Concentrated H₂SO₄, Copper turnings, Test tubes, Unknown nitrate samples

KLB Secondary Chemistry Form 3, Pages 151-153

NITROGEN AND ITS COMPOUNDS

Environmental Pollution by Nitrogen Compounds
Pollution Control and Environmental Solutions
Comprehensive Problem Solving - Nitrogen Chemistry

By the end of the lesson, the learner should be able to:
Explain sources of nitrogen pollution
Describe formation of acid rain
Discuss effects on environment and health
Evaluate pollution control measures

Teacher exposition: NOₓ from vehicles, HNO₃ formation in atmosphere, acid rain effects. Discussion: Chlorosis in plants, building corrosion, soil leaching, smog formation, health effects. Control measures: Catalytic converters, emission controls, proper fertilizer use.

Environmental pollution charts, Acid rain effect photos, Vehicle emission diagrams, Control measure illustrations
Case studies, Pollution control technology information, Group activity worksheets, Local environmental data
Scientific calculators, Comprehensive problem sets, Industrial data sheets, Experimental result tables

KLB Secondary Chemistry Form 3, Pages 154-157

NITROGEN AND ITS COMPOUNDS
NITROGEN AND ITS COMPOUNDS
SULPHUR AND ITS COMPOUNDS
SULPHUR AND ITS COMPOUNDS
SULPHUR AND ITS COMPOUNDS

Laboratory Practical Assessment - Nitrogen Compounds
Industrial Applications and Economic Importance
Chapter Review and Integration
Extraction of Sulphur
Allotropes of Sulphur
Physical Properties of Sulphur - Solubility

By the end of the lesson, the learner should be able to:
Demonstrate practical skills in nitrogen chemistry
Perform qualitative analysis of nitrogen compounds
Apply safety procedures correctly
Interpret experimental observations accurately
Synthesize all nitrogen chemistry concepts
Compare preparation methods for nitrogen compounds
Relate structure to properties and reactivity
Connect laboratory and industrial processes

Practical examination: Identify unknown nitrogen compounds using chemical tests. Prepare specified nitrogen compounds. Demonstrate proper laboratory techniques. Safety assessment. Written report on observations and conclusions.
Comprehensive review: Concept mapping of all nitrogen compounds and their relationships. Comparison tables: Preparation methods, properties, uses. Flow chart: Nitrogen cycle in industry and environment. Integration exercises connecting all topics.

Unknown nitrogen compounds, All laboratory chemicals and apparatus used in chapter, Safety equipment, Assessment rubrics
Economic data sheets, Industry case studies, Agricultural statistics, Cost-benefit analysis templates
Concept mapping materials, Comparison charts, Flow diagram templates, Integration worksheets
Charts showing periodic table, Diagram of Frasch process, Samples of sulphur compounds (pyrites, gypsum)
Powdered sulphur, Carbon(IV) sulphide, Evaporating dish, Glass rod, Hand lens, Boiling tubes, Filter paper, Beakers
Powdered sulphur, Water, Benzene, Methylbenzene, Carbon(IV) sulphide, Test tubes, Charts showing molecular structure

KLB Secondary Chemistry Form 3, Pages 119-157

SULPHUR AND ITS COMPOUNDS

Physical Properties of Sulphur - Effect of Heat
Chemical Properties of Sulphur - Reactions with Elements
Chemical Properties of Sulphur - Reactions with Acids
Uses of Sulphur and Introduction to Oxides
Preparation of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate the effect of heat on sulphur. Describe changes in color and viscosity of molten sulphur. Explain the molecular changes occurring during heating. Identify "flowers of sulphur".

Practical work: Experiment 2(b) - Heating sulphur and observing changes. Observation: Color changes from yellow to amber to reddish-brown to black. Testing viscosity by inverting test tube. Demonstration: Sublimation of sulphur vapour. Discussion: Breaking of S8 rings to form long chains.

Powdered sulphur, Test tubes, Bunsen burner, Cold surface for condensation, Thermometer, Safety equipment
Sulphur, Iron powder, Copper powder, Oxygen gas jar, Deflagrating spoon, Moist litmus papers, Test tubes, Bunsen burner
Sulphur powder, Concentrated HNO3, Concentrated H2SO4, Concentrated HCl, Barium chloride solution, Test tubes, Fume cupboard access
Charts showing uses of sulphur, Samples of vulcanized rubber, Fungicides, Industrial photographs, Textbook diagrams
Sodium sulphite, Dilute HCl, Round-bottomed flask, Delivery tubes, Gas jars, Concentrated H2SO4 for drying, Acidified potassium chromate(VI) paper

KLB Secondary Chemistry Form 4, Pages 164-165

SULPHUR AND ITS COMPOUNDS

Physical and Chemical Properties of Sulphur(IV) Oxide
Bleaching Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate the physical properties of SO2 gas. Test the solubility and acidity of SO Write equations for formation of sulphurous acid. Identify the acidic nature of SO

Practical work: Experiment 5 - Testing color, smell, solubility in water. Testing with dry and moist litmus papers. Universal indicator tests with water and NaOH. Formation of normal and acid salts. Recording observations in Table Safety: Proper ventilation due to toxic nature.

SO2 gas from previous preparation, Litmus papers, Universal indicator, 0.1M NaOH solution, Water, Test tubes, Safety equipment
Colored flower petals (red/blue), SO2 gas jars, Hand lens for observation, Charts comparing bleaching agents

KLB Secondary Chemistry Form 4, Pages 171-173

SULPHUR AND ITS COMPOUNDS

Reducing Action of Sulphur(IV) Oxide
Oxidising Action of Sulphur(IV) Oxide
Test for Sulphate and Sulphite Ions & Uses of SO2

By the end of the lesson, the learner should be able to:
Investigate SO2 as a reducing agent. Test reactions with various oxidizing agents. Write ionic equations for redox reactions. Identify color changes in redox reactions.

Practical work: Experiment 7 - Testing SO2 with acidified potassium dichromate(VI), potassium manganate(VII), bromine water, iron(III) chloride. Recording observations in Table 6. Color changes: Orange to green, purple to colorless, brown to colorless, yellow to pale green. Writing half-equations and overall equations.

SO2 gas, Acidified K2Cr2O7, Acidified KMnO4, Bromine water, Iron(III) chloride solution, Concentrated HNO3, Test tubes
SO2 gas jars, Magnesium ribbon, Deflagrating spoon, Hydrogen sulphide gas, Water droppers, Safety equipment
Sodium sulphate solution, Sodium sulphite solution, Barium chloride solution, Dilute HCl, Test tubes, Charts showing industrial uses

KLB Secondary Chemistry Form 4, Pages 173-176

SULPHUR AND ITS COMPOUNDS

Large-scale Manufacture of Sulphuric(VI) Acid - Contact Process
Properties of Concentrated Sulphuric(VI) Acid - Dehydrating Properties
Properties of Concentrated Sulphuric(VI) Acid - Oxidizing Properties
Properties of Concentrated Sulphuric(VI) Acid - Displacement Reactions
Reactions of Dilute Sulphuric(VI) Acid - With Metals

By the end of the lesson, the learner should be able to:
Describe the contact process for manufacturing H2SO Identify raw materials and conditions used. Explain the role of catalyst in the process. Draw flow diagrams of the contact process.
Investigate the oxidizing properties of concentrated H2SO Test reactions with metals and non-metals. Identify the products of oxidation reactions. Write balanced equations for redox reactions.

Study of flow diagram: Figure 12 - Contact process. Discussion: Raw materials (sulphur, air), burning sulphur to SO Purification: Electrostatic precipitation, drying with H2SO Catalytic chamber: V2O5 catalyst at 450°C, 2-3 atmospheres. Formation of oleum: H2S2O7. Safety and environmental considerations.
Practical work: Experiment 10 (continued) - Reactions with copper foil, zinc granules, charcoal. Testing evolved gases with acidified K2Cr2O7 paper, lime water. Observations: SO2 evolution, color changes. Discussion: H2SO4 → SO2 + H2O + [O]. Writing half-equations and overall equations.

Flow chart diagrams, Charts showing industrial plant, Samples of catalyst (V2O5), Photographs of Thika chemical plant, Calculator for percentage calculations
Concentrated H2SO4, Copper(II) sulphate crystals, Sucrose, Ethanol, KMnO4 solution, Test tubes, Beakers, Safety equipment, Fume cupboard
Copper foil, Zinc granules, Charcoal powder, Concentrated H2SO4, Acidified K2Cr2O7 paper, Lime water, Test tubes, Bunsen burner
Potassium nitrate crystals, Sodium chloride crystals, Concentrated H2SO4, Moist blue litmus paper, Concentrated ammonia, Test tubes, Bunsen burner
Magnesium ribbon, Zinc granules, Copper turnings, Dilute H2SO4, Test tubes, Burning splints, Reactivity series chart

KLB Secondary Chemistry Form 4, Pages 179-181
KLB Secondary Chemistry Form 4, Pages 183-184

SULPHUR AND ITS COMPOUNDS

Reactions of Dilute Sulphuric(VI) Acid - With Carbonates
Reactions of Dilute Sulphuric(VI) Acid - With Oxides and Hydroxides

By the end of the lesson, the learner should be able to:
Investigate reactions of dilute H2SO4 with carbonates. Test for carbon dioxide evolution. Explain why some reactions stop prematurely. Compare reactions of different metal carbonates.

Practical work: Experiment 12 - Reactions with sodium carbonate, zinc carbonate, calcium carbonate, copper(II) carbonate. Testing evolved gas with lime water. Recording observations in Table 1 Discussion: Formation of insoluble calcium sulphate coating. Effervescence and CO2 identification.

Sodium carbonate, Zinc carbonate, Calcium carbonate, Copper(II) carbonate, Dilute H2SO4, Lime water, Test tubes
Metal oxides (MgO, ZnO, CuO, PbO), NaOH solution, 2M H2SO4, Test tubes, Bunsen burner for warming

KLB Secondary Chemistry Form 4, Pages 185-186

SULPHUR AND ITS COMPOUNDS

Hydrogen Sulphide - Preparation and Physical Properties
Chemical Properties of Hydrogen Sulphide

By the end of the lesson, the learner should be able to:
Describe laboratory preparation of hydrogen sulphide. Set up apparatus for H2S preparation. State the physical properties of H2S. Explain the toxicity and safety precautions.

Demonstration: Figure 13 apparatus setup for H2S preparation. Reaction: FeS + 2HCl → FeCl2 + H2S. Collection over warm water due to solubility. Drying: Using anhydrous CaCl2 (not H2SO4). Properties: Colorless, rotten egg smell, poisonous, denser than air. Safety precautions in handling.

Iron(II) sulphide, Dilute HCl, Apparatus for gas generation, Anhydrous CaCl2, Gas jars, Safety equipment, Fume cupboard
H2S gas, Bromine water, Iron(III) chloride, KMnO4, K2Cr2O7, Metal salt solutions, Test tubes, Droppers

KLB Secondary Chemistry Form 4, Pages 187-188

SULPHUR AND ITS COMPOUNDS
CHLORINE AND ITS COMPOUNDS
CHLORINE AND ITS COMPOUNDS
CHLORINE AND ITS COMPOUNDS
CHLORINE AND ITS COMPOUNDS

Pollution Effects and Summary
Introduction and Preparation of Chlorine
Physical Properties of Chlorine
Chemical Properties of Chlorine - Reaction with Water
Chemical Properties of Chlorine - Reaction with Metals

By the end of the lesson, the learner should be able to:
Explain environmental pollution by sulphur compounds. Describe formation and effects of acid rain. Suggest methods to reduce sulphur pollution. Summarize key concepts of sulphur chemistry.

Discussion: Sources of SO2 pollution - burning fossil fuels, metal extraction, H2SO4 manufacture. Formation of acid rain: SO2 + H2O → H2SO3 → H2SO Effects: Plant damage, aquatic life destruction, building corrosion, soil acidification. Control measures: Scrubbing with Ca(OH)2, catalytic converters. Revision: Key reactions, properties, uses.

Charts showing pollution effects, Photographs of acid rain damage, Environmental data, Summary charts of reactions, Industrial pollution control diagrams
Manganese(IV) oxide, Concentrated HCl, Gas collection apparatus, Water, Concentrated H2SO4, Blue litmus paper, Gas jars
Preserved chlorine gas, Water trough, Gas jars, Observation tables, Safety equipment
Chlorine gas, Distilled water, Blue and red litmus papers, Colored flower petals, Gas jars, Boiling tubes
Magnesium ribbon, Iron wire, Chlorine gas, Deflagrating spoon, Combustion tube, Anhydrous CaCl2, Gas jars

KLB Secondary Chemistry Form 4, Pages 190-194

CHLORINE AND ITS COMPOUNDS

Chemical Properties of Chlorine - Reaction with Non-metals
Oxidising Properties of Chlorine
Reaction of Chlorine with Alkali Solutions
Oxidising Properties - Displacement Reactions
Test for Chloride Ions
Uses of Chlorine and its Compounds
Hydrogen Chloride - Laboratory Preparation

By the end of the lesson, the learner should be able to:
Investigate reactions of chlorine with non-metals. Demonstrate reaction with phosphorus and hydrogen. Write equations for non-metal chloride formation. Explain the vigorous nature of these reactions.
List the industrial uses of chlorine. Explain the use of chlorine in water treatment. Describe manufacture of chlorine compounds. Relate properties to uses of chlorine.

Practical work: Experiment 6.5 - Warming red phosphorus and lowering into chlorine. Demonstration: Burning hydrogen jet in chlorine. Observations: White fumes of phosphorus chlorides, hydrogen chloride formation. Writing equations: P4 + 6Cl2 → 4PCl3, H2 + Cl2 → 2HCl. Discussion: Formation of covalent chlorides.
Discussion: Industrial applications - HCl manufacture, bleaching agents for cotton and paper industries, water treatment and sewage plants. Study Figure 6.3(a) - bleaching chemicals. Applications: Chloroform (anaesthetic), solvents (trichloroethane), CFCs, PVC plastics, pesticides (DDT), germicides and fungicides. Q/A: Relating chemical properties to practical applications.

Red phosphorus, Hydrogen gas, Chlorine gas, Deflagrating spoon, Gas jars, Bunsen burner, Safety equipment
Sodium sulphite solution, Barium nitrate, Lead nitrate, Hydrogen sulphide gas, Aqueous ammonia, Chlorine gas, Test tubes
Sodium hydroxide solutions (dilute cold, concentrated hot), Chlorine gas, Beakers, Bunsen burner, Thermometer
Potassium bromide solution, Potassium iodide solution, Chlorine gas, Test tubes, Observation charts
Sodium chloride, Concentrated H2SO4, Lead(II) nitrate solution, Aqueous ammonia, Glass rod, Test tubes, Bunsen burner
Charts showing industrial uses, Samples of bleaching agents, PVC materials, Photographs of water treatment plants, Industrial application diagrams
Rock salt (NaCl), Concentrated H2SO4, Gas collection apparatus, Ammonia solution, Litmus papers, Water trough, Gas jars

KLB Secondary Chemistry Form 4, Pages 201
KLB Secondary Chemistry Form 4, Pages 205-207

CHLORINE AND ITS COMPOUNDS

Chemical Properties of Hydrogen Chloride
Large-scale Manufacture of Hydrochloric Acid
Uses of Hydrochloric Acid
Environmental Pollution by Chlorine Compounds and Summary

By the end of the lesson, the learner should be able to:
Prepare aqueous hydrogen chloride (hydrochloric acid). Investigate acid properties of HCl solution. Test reactions with metals, bases, and carbonates. Compare HCl in water vs organic solvents.

Practical work: Experiment 6.11 - Preparation of aqueous HCl using apparatus in Figure 6. Testing with metals (Zn, Fe, Mg, Cu), NaOH, carbonates, lead nitrate. Recording observations in Table 6.7. Testing HCl in methylbenzene - no acid properties. Discussion: Ionization in water vs molecular existence in organic solvents. Writing equations for acid reactions.

Distilled water, Filter funnel, Metals (Zn, Fe, Mg, Cu), NaOH solution, Carbonates, Lead nitrate, Methylbenzene, Indicators
Flow diagrams, Industrial photographs, Glass beads samples, Charts showing electrolysis processes, Safety equipment models
Samples of rusted and cleaned metals, Photographic materials, pH control charts, Industrial application videos, Water treatment diagrams
Environmental pollution charts, Ozone layer diagrams, DDT restriction documents, PVC waste samples, NEMA guidelines, Summary charts of reactions

KLB Secondary Chemistry Form 4, Pages 208-211