ELECTROCHEMISTRY

Redox Reactions and Oxidation Numbers
Oxidation Numbers in Naming and Redox Identification

By the end of the lesson, the learner should be able to:
Define redox reactions in terms of electron transfer
- State rules for assigning oxidation numbers
- Calculate oxidation numbers in compounds
- Identify oxidation and reduction processes

Q/A: Review previous knowledge
- Experiment 4.1: Iron filings + copper(II) sulphate
- Experiment 4.2: Iron(II) ions + hydrogen peroxide
- Discussion on oxidation number rules with examples

Iron filings, 1M CuSO₄, 1M FeSO₄, 2M NaOH, 20V H₂O₂, test tubes
Compound charts, calculators, student books, practice exercises

KLB Secondary Chemistry Form 4, Pages 108-116

ELECTROCHEMISTRY

Displacement Reactions - Metals and Halogens
Electrochemical Cells and Cell Diagrams

By the end of the lesson, the learner should be able to:
Explain displacement reactions using electron transfer
- Arrange metals and halogens by reactivity
- Predict displacement reactions
- Compare oxidizing powers of halogens

Experiment 4.3: Metal displacement reactions - systematic testing
- Experiment 4.4: Halogen displacement (FUME CUPBOARD)
- Tabulate results and arrange by reactivity

Various metals (Ca, Mg, Zn, Fe, Pb, Cu), metal salt solutions, halogens (Cl₂, Br₂, I₂), halide solutions
Metal electrodes, 1M metal salt solutions, voltmeters, salt bridges, connecting wires

KLB Secondary Chemistry Form 4, Pages 116-122

ELECTROCHEMISTRY

Standard Electrode Potentials
Calculating Cell EMF and Predicting Reactions
Types of Electrochemical Cells

By the end of the lesson, the learner should be able to:
Define standard electrode potential
- Describe standard hydrogen electrode
- List standard conditions
- Use electrode potential tables effectively
Describe functioning of primary and secondary cells
- Compare different cell types
- Explain fuel cell operation
- State applications of electrochemical cells

Study standard hydrogen electrode setup
- Discussion of standard conditions (25°C, 1M, 1 atm)
- Introduction to electrode potential series
- Practice reading potential tables
Study dry cell (Le Clanche) and lead-acid accumulator
- Hydrogen-oxygen fuel cell operation
- Compare cell types and applications
- Discussion on advantages/disadvantages

Standard electrode potential table, diagrams, charts showing standard conditions
Calculators, electrode potential data, worked examples, practice problems
Cell diagrams, sample batteries, charts showing cell applications

KLB Secondary Chemistry Form 4, Pages 129-133
KLB Secondary Chemistry Form 4, Pages 138-141

ELECTROCHEMISTRY

Electrolysis of Aqueous Solutions I
Electrolysis of Aqueous Solutions II

By the end of the lesson, the learner should be able to:
Define electrolysis and preferential discharge
- Investigate electrolysis of dilute sodium chloride
- Compare dilute vs concentrated solution effects
- Test products formed

Experiment 4.6(a): Electrolysis of dilute NaCl
- Experiment 4.6(b): Electrolysis of brine
- Test gases evolved
- Compare results and explain differences

Dilute and concentrated NaCl solutions, carbon electrodes, gas collection tubes, test equipment
U-tube apparatus, 2M H₂SO₄, 0.5M MgSO₄, platinum/carbon electrodes, gas syringes

KLB Secondary Chemistry Form 4, Pages 141-146

ELECTROCHEMISTRY

Effect of Electrode Material on Electrolysis

By the end of the lesson, the learner should be able to:
Compare inert vs reactive electrodes
- Investigate electrode dissolution
- Explain electrode selection importance
- Analyze copper purification process

Experiment 4.9: Electrolysis of CuSO₄ with carbon vs copper electrodes
- Weigh electrodes before/after
- Observe color changes
- Discussion on electrode effects

Copper and carbon electrodes, 3M CuSO₄ solution, accurate balance, beakers, connecting wires

KLB Secondary Chemistry Form 4, Pages 141-148

ELECTROCHEMISTRY

Factors Affecting Electrolysis

By the end of the lesson, the learner should be able to:
Identify factors affecting preferential discharge
- Explain electrochemical series influence
- Discuss concentration and electrode effects
- Predict electrolysis products

Review electrochemical series and discharge order
- Analysis of concentration effects on product formation
- Summary of all factors affecting electrolysis
- Practice prediction problems

Electrochemical series chart, summary tables, practice exercises, student books

KLB Secondary Chemistry Form 4, Pages 153-155

ELECTROCHEMISTRY

Applications of Electrolysis I

By the end of the lesson, the learner should be able to:
Describe electrolytic extraction of reactive metals
- Explain electroplating process
- Apply electrolysis principles to metal coating
- Design electroplating setup

Discussion: Extraction of Na, Mg, Al by electrolysis
- Practical: Electroplate iron nail with copper
- Calculate plating requirements
- Industrial applications

Iron nails, copper electrodes, CuSO₄ solution, power supply, industrial process diagrams

KLB Secondary Chemistry Form 4, Pages 155-157

ELECTROCHEMISTRY

Applications of Electrolysis II

By the end of the lesson, the learner should be able to:
Describe manufacture of NaOH and Cl₂ from brine
- Explain mercury cell operation
- Analyze industrial electrolysis processes
- Discuss environmental considerations

Study mercury cell for NaOH production
- Flow chart analysis of industrial processes
- Discussion on applications and environmental impact
- Purification of metals

Flow charts, mercury cell diagrams, environmental impact data, industrial case studies

KLB Secondary Chemistry Form 4, Pages 155-157

ELECTROCHEMISTRY

Faraday's Laws and Quantitative Electrolysis

By the end of the lesson, the learner should be able to:
State Faraday's laws of electrolysis
- Define Faraday constant
- Calculate mass deposited in electrolysis
- Relate electricity to amount of substance

Experiment 4.10: Quantitative electrolysis of CuSO₄
- Measure mass vs electricity passed
- Calculate Faraday constant
- Verify Faraday's laws

Accurate balance, copper electrodes, CuSO₄ solution, ammeter, timer, calculators

KLB Secondary Chemistry Form 4, Pages 161-164

ELECTROCHEMISTRY

Electrolysis Calculations I

By the end of the lesson, the learner should be able to:
Calculate mass of products from electrolysis
- Determine volumes of gases evolved
- Apply Faraday's laws to numerical problems
- Solve basic electrolysis calculations

Worked examples: Mass and volume calculations
- Problems involving different ions
- Practice with Faraday constant
- Basic numerical problems

Calculators, worked examples, practice problems, gas volume data, Faraday constant

KLB Secondary Chemistry Form 4, Pages 161-164

ELECTROCHEMISTRY

Electrolysis Calculations II
Advanced Applications and Problem Solving

By the end of the lesson, the learner should be able to:
Determine charge on ions from electrolysis data
- Calculate current-time relationships
- Solve complex multi-step problems
- Apply concepts to industrial situations
Solve examination-type electrochemistry problems
- Apply all concepts in integrated problems
- Analyze real-world electrochemical processes
- Practice complex calculations

Complex problems: Determine ionic charges
- Current-time-mass relationships
- Multi-step calculations
- Industrial calculation examples
Comprehensive problems combining redox, cells, and electrolysis
- Past examination questions
- Industrial case study analysis
- Advanced problem-solving techniques

Calculators, complex problem sets, industrial data, student books
Past papers, comprehensive problem sets, industrial case studies, calculators

KLB Secondary Chemistry Form 4, Pages 161-164
KLB Secondary Chemistry Form 4, Pages 108-164

ORGANIC CHEMISTRY II

Introduction to Alkanols and Nomenclature

By the end of the lesson, the learner should be able to:
Define alkanols and identify functional group
- Apply nomenclature rules for alkanols
- Draw structural formulae of simple alkanols
- Compare alkanols with corresponding alkanes

Q/A: Review alkanes, alkenes from Form 3
- Study functional group -OH concept
- Practice naming alkanols using IUPAC rules
- Complete Table 6.2 - alkanol structures

Molecular models, Table 6.1 and 6.2, alkanol structure charts, student books

KLB Secondary Chemistry Form 4, Pages 167-170

ORGANIC CHEMISTRY II

Isomerism in Alkanols
Laboratory Preparation of Ethanol

By the end of the lesson, the learner should be able to:
Explain positional and chain isomerism
- Draw isomers of given alkanols
- Name different isomeric forms
- Classify isomers as primary, secondary, or tertiary

Study positional isomerism examples (propan-1-ol vs propan-2-ol)
- Practice drawing chain isomers
- Exercises on isomer identification and naming
- Discussion on structural differences

Isomer structure charts, molecular models, practice worksheets, student books
Sugar, yeast, warm water, conical flask, delivery tube, lime water, thermometer

KLB Secondary Chemistry Form 4, Pages 170-171

ORGANIC CHEMISTRY II

Industrial Preparation and Physical Properties
Chemical Properties of Alkanols I

By the end of the lesson, the learner should be able to:
Explain hydration of ethene method
- Compare laboratory and industrial methods
- Analyze physical properties of alkanols
- Relate properties to molecular structure

Study ethene hydration using phosphoric acid catalyst
- Compare fermentation vs industrial methods
- Analyze Table 6.3 - physical properties
- Discussion on hydrogen bonding effects

Table 6.3, industrial process diagrams, ethene structure models, property comparison charts
Ethanol, sodium metal, universal indicator, concentrated H₂SO₄, ethanoic acid, test tubes

KLB Secondary Chemistry Form 4, Pages 171-173

ORGANIC CHEMISTRY II

Chemical Properties of Alkanols II
Uses of Alkanols and Health Effects
Introduction to Alkanoic Acids

By the end of the lesson, the learner should be able to:
Investigate oxidation and esterification reactions
- Test oxidizing agents on ethanol
- Prepare esters from alkanols
- Explain dehydration reactions
Define alkanoic acids and functional group
- Apply nomenclature rules
- Draw structural formulae
- Compare with alkanols

Complete Experiment 6.2: Test with acidified K₂Cr₂O₇ and KMnO₄
- Observe color changes
- Esterification with ethanoic acid
- Study dehydration conditions
Study carboxyl group (-COOH) structure
- Practice naming using IUPAC rules
- Complete Table 6.5 and 6.6
- Compare functional groups of alkanols and acids

Acidified potassium chromate/manganate, ethanoic acid, concentrated H₂SO₄, heating apparatus
Charts showing alkanol uses, health impact data, methylated spirit samples, discussion materials
Alkanoic acid structure charts, Table 6.5 and 6.6, molecular models, student books

KLB Secondary Chemistry Form 4, Pages 173-176
KLB Secondary Chemistry Form 4, Pages 177-179

ORGANIC CHEMISTRY II

Laboratory Preparation of Ethanoic Acid

By the end of the lesson, the learner should be able to:
Prepare ethanoic acid by oxidation
- Write equations for preparation
- Set up oxidation apparatus
- Identify product by testing

Experiment 6.3: Oxidize ethanol using acidified KMnO₄
- Set up heating and distillation apparatus
- Collect distillate at 118°C
- Test product properties

Ethanol, KMnO₄, concentrated H₂SO₄, distillation apparatus, thermometer, round-bottom flask

KLB Secondary Chemistry Form 4, Pages 179-180

ORGANIC CHEMISTRY II

Physical and Chemical Properties of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Investigate chemical reactions of ethanoic acid
- Test with various reagents
- Write chemical equations
- Analyze acid strength

Experiment following Table 6.8: Test ethanoic acid with indicators, metals, carbonates, bases
- Record observations
- Write equations
- Discuss weak acid behavior

2M ethanoic acid, universal indicator, Mg strip, Na₂CO₃, NaOH, phenolphthalein, test tubes

KLB Secondary Chemistry Form 4, Pages 180-182

ORGANIC CHEMISTRY II

Esterification and Uses of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Explain ester formation process
- Write esterification equations
- State uses of alkanoic acids
- Prepare simple esters

Complete esterification experiments
- Study concentrated H₂SO₄ as catalyst
- Write general esterification equation
- Discuss applications in food, drugs, synthetic fibres

Ethanoic acid, ethanol, concentrated H₂SO₄, test tubes, heating apparatus, cold water

KLB Secondary Chemistry Form 4, Pages 182-183

ORGANIC CHEMISTRY II

Introduction to Detergents and Soap Preparation
Mode of Action of Soap and Hard Water Effects

By the end of the lesson, the learner should be able to:
Define detergents and classify types
- Explain saponification process
- Prepare soap in laboratory
- Compare soapy and soapless detergents
Explain soap molecule structure
- Describe cleaning mechanism
- Investigate hard water effects
- Compare soap performance in different waters

Study soap vs soapless detergent differences
- Experiment 6.5: Saponify castor oil with NaOH
- Add salt for salting out
- Test soap formation
Study hydrophobic and hydrophilic ends
- Demonstrate micelle formation
- Test soap in distilled vs hard water
- Observe scum formation
- Write precipitation equations

Castor oil, 4M NaOH, NaCl, evaporating dish, water bath, stirring rod, filter paper
Soap samples, distilled water, hard water (CaCl₂/MgSO₄ solutions), test tubes, demonstration materials

KLB Secondary Chemistry Form 4, Pages 183-186
KLB Secondary Chemistry Form 4, Pages 186-188

ORGANIC CHEMISTRY II

Soapless Detergents and Environmental Effects

By the end of the lesson, the learner should be able to:
Explain soapless detergent preparation
- Compare advantages/disadvantages
- Discuss environmental impact
- Analyze pollution effects

Study alkylbenzene sulphonate preparation
- Compare Table 6.9 - soap vs soapless
- Discussion on eutrophication and biodegradability
- Environmental awareness

Flow charts of detergent manufacture, Table 6.9, environmental impact data, sample detergents

KLB Secondary Chemistry Form 4, Pages 188-191

ORGANIC CHEMISTRY II

Introduction to Polymers and Addition Polymerization

By the end of the lesson, the learner should be able to:
Define polymers, monomers, and polymerization
- Explain addition polymerization
- Draw polymer structures
- Calculate polymer properties

Study polymer concept and terminology
- Practice drawing addition polymers from monomers
- Examples: polyethene, polypropene, PVC
- Calculate molecular masses

Polymer samples, monomer structure charts, molecular models, calculators, polymer formation diagrams

KLB Secondary Chemistry Form 4, Pages 191-195

ORGANIC CHEMISTRY II

Addition Polymers - Types and Properties

By the end of the lesson, the learner should be able to:
Identify different addition polymers
- Draw structures from monomers
- Name common polymers
- Relate structure to properties

Study polystyrene, PTFE, perspex formation
- Practice identifying monomers from polymer structures
- Work through polymer calculation examples
- Properties analysis

Various polymer samples, structure identification exercises, calculation worksheets, Table 6.10

KLB Secondary Chemistry Form 4, Pages 195-197

ORGANIC CHEMISTRY II

Condensation Polymerization and Natural Polymers

By the end of the lesson, the learner should be able to:
Explain condensation polymerization
- Compare with addition polymerization
- Study natural polymers
- Analyze nylon formation

Study nylon 6,6 formation from diamine and dioic acid
- Natural polymers: starch, protein, rubber
- Vulcanization process
- Compare synthetic vs natural

Nylon samples, rubber samples, condensation reaction diagrams, natural polymer examples

KLB Secondary Chemistry Form 4, Pages 197-200

ORGANIC CHEMISTRY II

Condensation Polymerization and Natural Polymers

By the end of the lesson, the learner should be able to:
Explain condensation polymerization
- Compare with addition polymerization
- Study natural polymers
- Analyze nylon formation

Study nylon 6,6 formation from diamine and dioic acid
- Natural polymers: starch, protein, rubber
- Vulcanization process
- Compare synthetic vs natural

Nylon samples, rubber samples, condensation reaction diagrams, natural polymer examples

KLB Secondary Chemistry Form 4, Pages 197-200

ORGANIC CHEMISTRY II

Polymer Properties and Applications
Comprehensive Problem Solving and Integration

By the end of the lesson, the learner should be able to:
Compare advantages and disadvantages of synthetic polymers
- State uses of different polymers
- Discuss environmental concerns
- Analyze polymer selection
Solve complex problems involving alkanols and acids
- Apply knowledge to practical situations
- Integrate polymer concepts
- Practice examination questions

Study Table 6.10 - polymer uses
- Advantages: strength, lightness, moldability
- Disadvantages: non-biodegradability, toxic gases
- Application analysis
Worked examples on organic synthesis
- Problem-solving on isomers, reactions, polymers
- Integration of all unit concepts
- Practice examination-style questions

Table 6.10, polymer application samples, environmental impact studies, product examples
Comprehensive problem sets, past examination papers, calculators, organic chemistry summary charts

KLB Secondary Chemistry Form 4, Pages 200-201
KLB Secondary Chemistry Form 4, Pages 167-201

RADIOACTIVITY

Introduction, Nuclear Stability and Types of Radioactivity
Types of Radiation and Their Properties

By the end of the lesson, the learner should be able to:
Define nuclide, isotope, and radioisotope
- Compare nuclear vs chemical reactions
- Explain neutron/proton ratios
- Distinguish natural from artificial radioactivity

Q/A: Review atomic structure from Form 2
- Study Table 7.1 - nuclear vs chemical reactions
- Analysis of neutron/proton ratios and nuclear stability
- Discussion on natural vs artificial radioactivity

Periodic table, atomic structure charts, Table 7.1, nuclear stability diagrams
Radiation type charts, penetration diagrams, electric field illustrations, safety equipment charts

KLB Secondary Chemistry Form 4, Pages 199-201

RADIOACTIVITY

Radioactive Decay and Half-Life Concept
Half-Life Calculations and Problem Solving

By the end of the lesson, the learner should be able to:
Define half-life of radioactive isotopes
- Plot radioactive decay curves
- Calculate remaining amounts after decay
- Apply conservation of mass and energy

Study Table 7.2 - iodine-131 decay data
- Plot decay graph using given data
- Calculate fractions remaining after multiple half-lives
- Practice basic half-life problems

Graph paper, Table 7.2 data, calculators, decay curve examples, half-life data table
Calculators, comprehensive problem sets, worked examples, isotope half-life comparison tables

KLB Secondary Chemistry Form 4, Pages 204-206

RADIOACTIVITY

Nuclear Reactions and Equations

By the end of the lesson, the learner should be able to:
Write balanced nuclear equations
- Apply conservation laws for mass and atomic numbers
- Explain alpha and beta emission effects
- Balance complex nuclear reactions

Practice writing nuclear equations for alpha emission
- Study beta emission examples
- Apply mass and atomic number conservation
- Balance various nuclear reactions with missing nuclides

Nuclear equation examples, periodic table, conservation law charts, practice worksheets

KLB Secondary Chemistry Form 4, Pages 205-207

RADIOACTIVITY

Radioactive Decay Series and Sequential Reactions
Nuclear Fission and Chain Reactions
Nuclear Fusion and Energy Comparisons
Medical and Diagnostic Applications

By the end of the lesson, the learner should be able to:
Explain sequential radioactive decay
- Trace decay series pathways
- Identify stable end products
- Complete partial decay series
Define nuclear fusion process
- Compare fusion with fission processes
- Write fusion equations
- Explain stellar energy production and fusion applications

Study thorium-232 decay series example
- Trace sequential alpha and beta emissions
- Identify stable lead-208 endpoint
- Practice completing decay series with missing nuclides
Study hydrogen fusion examples
- Compare fusion vs fission characteristics and energy yields
- Stellar fusion processes
- Hydrogen bomb vs nuclear reactor principles

Decay series charts, thorium series diagram, nuclide stability charts, practice decay series
Fission reaction diagrams, chain reaction illustrations, nuclear reactor diagrams, energy calculation examples
Fusion reaction diagrams, comparison tables, stellar fusion charts, energy comparison data
Medical radioisotope charts, treatment procedure diagrams, diagnostic equipment images, case studies

KLB Secondary Chemistry Form 4, Pages 206-207
KLB Secondary Chemistry Form 4, Pages 207-208

RADIOACTIVITY

Industrial, Agricultural and Dating Applications

By the end of the lesson, the learner should be able to:
Explain industrial leak detection
- Describe agricultural monitoring techniques
- Discuss carbon-14 dating principles
- Analyze food preservation methods

Study leak detection using short half-life isotopes
- Carbon-14 dating of archaeological materials
- Phosphorus tracking in agriculture
- Gamma radiation food preservation

Carbon dating examples, agricultural application charts, industrial use diagrams, food preservation data

KLB Secondary Chemistry Form 4, Pages 208-209

RADIOACTIVITY

Radiation Hazards and Environmental Impact

By the end of the lesson, the learner should be able to:
Identify radiation health hazards
- Explain genetic mutation effects
- Discuss major nuclear accidents
- Analyze long-term environmental contamination

Study Chernobyl and Three Mile Island accidents
- Genetic mutation and cancer effects
- Long-term radiation exposure consequences
- Nuclear waste disposal challenges

Accident case studies, environmental impact data, radiation exposure charts, contamination maps

KLB Secondary Chemistry Form 4, Pages 209-210

RADIOACTIVITY

Radiation Hazards and Environmental Impact

By the end of the lesson, the learner should be able to:
Identify radiation health hazards
- Explain genetic mutation effects
- Discuss major nuclear accidents
- Analyze long-term environmental contamination

Study Chernobyl and Three Mile Island accidents
- Genetic mutation and cancer effects
- Long-term radiation exposure consequences
- Nuclear waste disposal challenges

Accident case studies, environmental impact data, radiation exposure charts, contamination maps

KLB Secondary Chemistry Form 4, Pages 209-210

RADIOACTIVITY

Safety Measures and International Control
Half-Life Problem Solving and Graph Analysis

By the end of the lesson, the learner should be able to:
Explain radiation protection principles
- Describe proper storage and disposal methods
- Discuss IAEA role and standards
- Analyze monitoring and control systems
Solve comprehensive half-life problems
- Analyze experimental decay data
- Plot and interpret decay curves
- Determine half-lives graphically

Study IAEA guidelines and international cooperation
- Radiation protection protocols and ALARA principle
- Safe storage, transport and disposal methods
- Environmental monitoring systems
Plot decay curves from experimental data
- Determine half-lives from graphs
- Analyze count rate vs time data
- Complex half-life calculation problems

IAEA guidelines, safety protocol charts, monitoring equipment diagrams, international cooperation data
Graph paper, experimental data sets, calculators, statistical analysis examples, comprehensive problem sets

KLB Secondary Chemistry Form 4, Pages 209-210
KLB Secondary Chemistry Form 4, Pages 199-210

RADIOACTIVITY

Nuclear Equations and Conservation Laws

By the end of the lesson, the learner should be able to:
Balance complex nuclear equations
- Complete nuclear reaction series
- Identify unknown nuclides using conservation laws
- Apply mass-energy relationships

Practice balancing nuclear reactions with multiple steps
- Complete partial decay series
- Identify missing nuclides using conservation principles
- Mass-energy calculation problems

Nuclear equation worksheets, periodic table, decay series diagrams, conservation law examples

KLB Secondary Chemistry Form 4, Pages 199-210