ACIDS, BASES AND SALTS.

Strength of acids. Acids in aqueous form.

By the end of the lesson, the learner should be able to:


Define an acid in terms of hydrogen ions.

Explain strength of acids in aqueous form in terms of number of hydrogen ions present.

Class experiments: investigate reactions of magnesium and zinc carbonate with different acids.
Make and record observations in tabular form.
Make deductions from the observations.
Write relevant chemical equations and ionic equations.
Detailed discussion leading to the definition of an acid and explanation of strength of an acid.

Magnesium strip, zinc carbonate,
2M HCl,
2M H2SO4,
2M ethanoic acid.

K.L.B. BK IV
Pages 1-4

ACIDS, BASES AND SALTS.

pH values of acids. Electrical conductivities of aqueous acids.
Definition of a base in terms of hydroxide ions.
Neutralization reaction.

By the end of the lesson, the learner should be able to:
Determine strength of acids using pH values.

Determine strengths of acids by comparing their electrical conductivities.

Classify acids as either strong or weak in terms of partial dissociations in aqueous solutions.

Define a base in terms of hydroxide ions.

Q/A: review determination of strength of acids using a litmus paper and pH scale.
Class / group experiments: record colour of universal indicator in
2M HCl and 2M ethanoic acid.
Set up voltameters of 2M HCl and 2M ethanoic acid in turns.
Record amounts of current .
Discuss the observations.
Write corresponding ionic equations.

Teacher demonstration:
Dissolve calcium hydroxide in water.
Carry out litmus test on the resulting solution.
Discuss the results; hence define a base in terms of hydroxide ions.

Universal
indicator,
2M HCl,
2M ethanoic acid,
dry cells,
carbon electrodes,
milli-ammeters,
wires, switches etc.

Red litmus paper, calcium hydroxide solid.
1M HCl,
Calcium hydroxide,
universal indicator.

K.L.B. BK IV
Pages 4-6
K.L.B. BK IV
Pages 6-7

ACIDS, BASES AND SALTS.

Strength of bases.

By the end of the lesson, the learner should be able to:
Compare strengths of bases using pH values and electrical conductivity.


Classify bases/ alkali as either strong or weak in terms of complete / partial ionization.

Carry out pH tests of 2M NaOH and 2M ammonia solution using universal indicator solutions; and observe colour changes.

Carry out electrical conductivity tests of voltameters of the above solutions.

Discussion: relate number of hydroxide ions to pH values and electrical conductivity of bases.

2M NaOH,
2M ammonia solution, universal indicator solutions, dry cells,
carbon electrodes,
milliammeters,
wires, switches etc

K.L.B. BK IV
Pages 7-9

ACIDS, BASES AND SALTS.

Dissolving hydrogen chloride gas in water / methylbenzene.
Dissolving ammonia gas in water/ methylbenzene.

By the end of the lesson, the learner should be able to:
Define a polar and a non-polar solvent.

Teacher demonstration:
Dissolving HCl gas in different solvents.
Discuss the observations.
Write down related balanced chemical equations.

Ammonia gas,
Methylbenzene, hydrogen chloride gas.
Methylbenzene.

K.L.B. BK IV
Pages 9-11

ACIDS, BASES AND SALTS.

Amphoteric oxides.

By the end of the lesson, the learner should be able to:
Define an amphoteric oxide.
Identify some amphoteric oxides.

Class experiment:
Carry out acid / base reactions with metal oxides.
Q/A: make deductions from the results.
Writing and balancing relevant equations.

2M Nitric acid
2M NaOH,
HNO3.
Amphoteric oxides.

K.L.B. BK IV
Pages 12-14

ACIDS, BASES AND SALTS.

Precipitation Reactions.
Solubility of chlorides sulphites and sulphates.
Equations for formation of insoluble chlorides, sulphites and sulphates.

By the end of the lesson, the learner should be able to:
Define a precipitate.
Write ionic equations showing formation of precipitates.

Find out cations that form (in)soluble chlorides, sulphates and sulphites.

Q/A: review definition of a salt.
Class experiment;
Add sodium carbonate or a suitable carbonate to various salt solutions containing Mg2+, Al3+, Ca2+, etc.
Make observations and discuss the results.


Class experiments: measure 2cc of 0.1M solution containing Pb2+ into a test tube.
Add drops of 2M NaCl solution.
(Later 2M Sodium Sulphate and 2M Sodium Sulphate).
Warm the mixture and make observations.
Repeat the procedure using other salt solutions containing other ions.
Tabulate the results.

Soluble carbonates e.g. Na2CO3, K2CO3, (NH4)2CO3
Salt solutions containing Mg2+, Al3+, Ca2+, etc.

0.1M solution containing Pb2+, 2M NaCl solution, 2M sodium sulphate, source of heating.
student book

K.L.B. BK IV
Pages 14-16
K.L.B. BK IV
Pages 16-17

ACIDS, BASES AND SALTS.

Complex ions.

By the end of the lesson, the learner should be able to:
Explain formation of complex ions.

Add drops of 2M sodium hydroxide / 2M ammonia solution to a solution containing Mg2+, Zn2+, etc.

Make observations and discuss the results.

2M Sodium hydroxide (2M ammonia solution),
solution containing Mg2+, Zn2+, etc.

K.L.B. BK IV
Pages 18-20

ACIDS, BASES AND SALTS.

Solubility of a salt at a given temperature.

By the end of the lesson, the learner should be able to:
Define the term solubility.
Determine solubility of a given salt at room temperature.

Q/A: review the terms saturated, unsaturated solutions & crystallization.
Class experiment: determine mass of a solute that dissolves in 100cc of water at room temperature.

Suitable solutes.

K.L.B. BK IV
Pages 20-21

ACIDS, BASES AND SALTS.

Problems solving on solubility.

By the end of the lesson, the learner should be able to:
Solve problems involving solubility of a solute in a solvent at a given temperature.

Worked examples.
Supervised practice.
Written assignment.

Evaporating dish, watch glass, heating source, thermometer.

K.L.B. BK IV
Pages 21-22

ACIDS, BASES AND SALTS.
ACIDS, BASES AND SALTS.
ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Effect of temperature on solubility of a solute in a solvent.
Effects of various salts on soap.
Removal of hardness of water.
Endothermic and Exothermic Reactions.

By the end of the lesson, the learner should be able to:
Investigate the effect of temperature on solubility of a solute in a solvent.
Identify ions for hardness of water.
Identify methods of removing hardness of water.
State merits & demerits of hard water.

Experiments involving solubility of KClO3 at different temperatures.
Note temperatures at which crystallization occurs.
Oral questions and discussion.

Review results of above experiments.

Probing questions & brief discussion.

Assignment.

KClO3 thermometers, source of heat.
distilled water, tap water, rainwater, dilute solution of sodium chloride and solutions containing Ca2+ and Zn2+.
student book
Ammonium nitrate,
Sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 22-25
K.L.B. BK IV
Pages 27-29

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Energy level diagrams.

By the end of the lesson, the learner should be able to:
Represent endothermic reactions with exothermic reactions with energy level diagrams.

Probing questions on relative energies of reactants and products in endothermic and exothermic and endothermic reactions.

student book

K.L.B. BK IV
Pages 33-35

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy Notation. Change of state.
CAT

By the end of the lesson, the learner should be able to:
Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of given substances.

Dissolve known masses of ammonia nitrate / sodium hydroxide in known volumes of water.
Determine temperature changes.
Calculate molar heat of solution. Supervised practice.

Ammonia nitrate / sodium hydroxide, thermometers.

K.L.B. BK IV
Pages 40-41

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of H2SO4.
Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Determine molar heat of solution of H2SO4.
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Conc. H2SO4, thermometers.
Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 42-45
K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Standard enthalpy changes.

By the end of the lesson, the learner should be able to:
Define the term standard enthalpy change.
Denote standard enthalpy change with the correct notation.

Exposition & brief discussion.

student book

K.L.B. BK IV
Pages 54-56

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Hess?s Law.
Heat of solution hydration energy and lattice energy.
Heat values of fuels.

By the end of the lesson, the learner should be able to:
State Hess?s law.

Solve problems related to Hess?s law.
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 56-57
K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.
RATES OF REACTION & REVERSIBLE REACTIONS.

Environmental effects of fuels.
Effect of temperature of reactants on rate of reaction.

By the end of the lesson, the learner should be able to:
Outline some environmental effects of fuels.
Identify measures taken to reduce environmental
pollution.

Q/A & open discussion.

student book
Sodium thiosulphate heated at different temperatures, dilute HCl, stopwatches.
Graph papers.

K.L.B. BK IV
Pages 67-68

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change in surface area of reactants on the rate of a reaction.
Effect of a suitable catalyst on the rate of a reaction

By the end of the lesson, the learner should be able to:
Explain the effect of change in surface area on the rate of a reaction.

Group experiment/ teacher demonstration.

Compare reactions of marble chips with dilute HCl and that of marble chips powder with equally diluted HCl.

Collect evolved gas in each case.

Teacher asks probing questions related to the observations made.

Marble chips, marble chips powder, syringes, conical flasks with stoppers, 1M HCl.
Hydrogen peroxide, manganese (IV) oxide.

K.L.B. BK IV
Pages 83-85

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of light on rate of specific reactions.
Reversible reactions.

By the end of the lesson, the learner should be able to:
Identify reactions that are affected by light.

Teacher demonstration: decomposition of silver bromide in the presence of light.
Mention other examples of reactions affected by light.

Silver bromide.
Crystals of hydrated copper (II) sulphate.

K.L.B. BK IV
Pages 89-91

RATES OF REACTION & REVERSIBLE REACTIONS.

State of equilibrium in chemical reactions.
Le Chatelier?s Principle.
Effect of change of pressure and temperature on equilibrium shift.
The Haber Process.

By the end of the lesson, the learner should be able to:
Define the term equilibrium as used in reversible reactions.
Write down equations of reversible reactions in a state of equilibrium.

Explain the effect of change of pressure & te,perature on equilibrium shift.

Brief discussion, giving examples of chemical equations for reversible reactions.
Q/A: review kinetic theory of matter.
Q/A & discussion on effect of change of pressure / temperature on shifting of equilibrium; giving specific examples of chemical equations.
Written assignment.

student book
Add 2M sodium hydroxide,

K.L.B. BK IV
Pages 94-95
K.L.B. BK IV
Pages 97-101

RATES OF REACTION & REVERSIBLE REACTIONS.
ELECTRO-CHEMISTRY.

The Contact Process.
Redox reactions.

By the end of the lesson, the learner should be able to:
Explain how change of temperature and pressure affect rate of manufacture of sulphur (VI) acid.

Probing questions and brief discussion.

Assignment.

student book

K.L.B. BK IV
Pages 103-104

ELECTRO-CHEMISTRY.

Oxidizing Numbers.

By the end of the lesson, the learner should be able to:
Outline rules of assigning oxidation numbers.
Determine the oxidation numbers of an element in a given compound.
Explain the use of oxidation numbers in naming compounds.

Exposition and giving specific examples.
Work out oxidizing number of elements in given compounds.
Copy and complete a table of compounds containing elements that more than one oxidation number.

student book

K.L.B. BK IV
Pages 109-116

ELECTRO-CHEMISTRY.

Displacement reactions.
The oxidizing power of an element.

By the end of the lesson, the learner should be able to:
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.

Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.
Halogens:
Cl2 (g),
Br2 (l),
I2 (s).
Halides:
KCl, KBr, KI.

K.L.B. BK IV
Pages 116-120

ELECTRO-CHEMISTRY.

Cell diagrams.
Standard Electrode Potentials.
Standard electrode potential series.

By the end of the lesson, the learner should be able to:
Define the terms electrode, potential and e.m.f. of an electrochemical cell.
Describe components of a cell diagram.
Draw cell diagrams using correct notations.
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.

Teacher demonstration: Zinc/ copper cell.
Q/A & discussion: changes in oxidation numbers.
Exposition: cell diagram and deducing the direction of electron flow.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

Zinc/ copper cell.
student book

K.L.B. BK IV
Pages 123-128
K.L.B. BK IV
Pages 131-133

ELECTRO-CHEMISTRY.

Emf of a cell.
Possibility of a reaction to take place.

By the end of the lesson, the learner should be able to:
Calculate emf of a cell using standard electrodes potentials.

Q/A: review half-cells.
Worked examples; supervised practice.
Assignment.

student book

K.L.B. BK IV
Pages 133-136

ELECTRO-CHEMISTRY.

Primary and secondary chemical cells.

By the end of the lesson, the learner should be able to:
Describe the functioning of primary and secondary chemical cells.

Exposition of new concepts and brief discussion
Assignment.

student book

K.L.B. BK IV
Pages 138-141

ELECTRO-CHEMISTRY.

Electrolysis of dilute NaCl.
Electrolysis of brine.

By the end of the lesson, the learner should be able to:
Define the term electrolysis.
Explain the concept of preferential discharge of ions.

Teacher demonstration: electrolysis of dilute sodium chloride with carbon electrodes.
Test for gases collected.
Write down equations of reactions at each electrode.
Discussion: preferential discharge of ions at electrodes.

Dilute sodium chloride voltameter.
Brine voltameter.

K.L.B. BK IV
Pages 141-144

ELECTRO-CHEMISTRY.

Electrolysis of dilute sulphuric (VI) acid.
Factors affecting electrolysis.
Application of electrolysis.
Faraday?s law of electrolysis.

By the end of the lesson, the learner should be able to:
Identify products of electrolysis of dilute sulphuric (VI) acid.
Describe some applications of electrolysis.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Probing questions and brief discussion on applications of electrolysis.
Practical assignment on electrolysis: electroplating an iron nail with a suitable metal.

Sulphuric acid voltameter.
student book
Suitable voltameter.
Weighing balance, stop watch, copper sulphate voltameter.

K.L.B. BK IV
Pages 146-148
K.L.B. BK IV
Pages 155-7

METALS

Ores of some metals.
Occurrence and extraction of sodium.

By the end of the lesson, the learner should be able to:


Name the chief ores of some metals.

Exposition and brief discussion.

Chart: Down?s cell.

K.L.B. BK IV
Pages 168-9

METALS

Occurrence and extraction of aluminium.
Occurrence and extraction of iron.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of aluminium.

Brief discussion.
Write relevant chemical equations.

student book
Chart: Blast furnace.

K.L.B. BK IV
Pages 171-3

METALS

Occurrence and extraction of zinc.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of zinc by electrolysis and reduction methods.

Brief discussion.
Write relevant chemical equations.

Flow chart: extraction of Zinc.

K.L.B. BK IV
Pages 175-9

METALS

Extraction of lead.
Occurrence and extraction of copper.
Physical properties of some metals.

By the end of the lesson, the learner should be able to:
Explain how lead is extracted.
State general properties of metals.
Explain the difference in physical properties of metals.

Q/A & brief discussion.
Write balanced chemical equations leading to extraction of lead.

Compare physical properties of some metals as summarized in a chart.
Q/A & discussion based on physical properties.

Flow chart: extraction of lead.
Flow chart: extraction of copper.
student book

K.L.B. BK IV
Pages 179-80
K.L.B. BK IV
Pages 183-4

METALS

Reaction of metals with oxygen.

By the end of the lesson, the learner should be able to:
Explain effect of burning metals in air.

Teacher demonstration / Group experiments.
Burning some metals in air.
Write relevant equations.
Brief discussion.

Common lab. metals.

K.L.B. BK IV
Pages 184-6

METALS

Reaction of metals with cold water and steam.

By the end of the lesson, the learner should be able to:
Describe reaction of metals with cold water and steam.

Arrange the metals in order of reactivity with cold water and steam.

Class experiments:
Investigate reaction of some metals with cold water and steam.
Analyse the results.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 186-9

METALS

Reaction of metals with chlorine.

By the end of the lesson, the learner should be able to:
Describe the reaction of metals with chlorine.

Teacher demonstration in a fume cupboard / in the open.
Investigate reaction of metals with chorine
Write corresponding equations.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 189-191

METALS
METALS
ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Reaction of metals with acids.
Uses of metals.
Environmental effects of extraction of metals.
Alkanols (Alcohols).

By the end of the lesson, the learner should be able to:
Describe and explain reaction of metals with acids.
Identify some environmental effects of extraction of metals.

Group experiments: investigate reaction of metals with dilute acids.
Teacher demonstration: investigate reaction of metals with concentrated acids.
Discuss the observations made and write relevant chemical equations.

Oral questions and open discussion.

Assignment / Topic review.

Metals: Al, Zn, Fe, Cu.
Acids; HCl, HNO3, H2SO4.
student book

K.L.B. BK IV
Pages 191-4
K.L.B. BK IV
Pages 197-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Nomenclature of alkanols.
Isomerism in alkanols.

By the end of the lesson, the learner should be able to:
Name and draw the structure of simple alkanols.

Guided discovery of naming system for alkanols.
Draw and name structures of alkanols.

student book

K.L.B. BK IV
Pages 206-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Preparation of ethanol in the lab.

By the end of the lesson, the learner should be able to:
Describe preparation of ethanol in the laboratory.

Group experiments / teacher demonstration.

Discuss the fermentation process.

Calcium hydroxide solution, sugar solution, yeast.

K.L.B. BK IV
Pages 210-11